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In the region around 1600 c m ~ all benzene derivatives exhibit IR as well as Raman I, bands of medium intensity due to oi4t-c$-phase stretching vibrations of the ring (compare Fig. 4.1-1 3). Occasionally, these bands may overlap with -NH deformation vibrations. The absence of bands in the region around 1620 to 1560 cm both in the IR and the Raman spectrum very likely points to the absence of benzene rings. Further interpretation is based on the Raman bands around 1000 c m ~ representing combined stretching and ' deformation vibrations of the ring atoms, together with those of bending vibrations observed at lower frequencies. Mono substitution is characterized by a pair of bands at 1000 and 1030 cm (Fig. 4.1-13A). In the case of mera di substitution, the band at 1030 is not observed (Fig. 4.1-13B), while orrho di substitution results in a very strong band between 1055 and 1015 cm-'; para di substitution finally is characterized by the absence of a strong band in the region around 1000 cm (Fig. 4.1-13C). In Table 4.1-4 other significant Raman bands as well as IR bands are included which may be used to confirm the interpretation of the spectra. The characteristic pattern of overtone bands and combination vibrations between 2000 and 1660 cm-' in the IR spectra of alkyl substituted benzene derivatives as well as the out-of-plane deformation vibrations of the hydrogen atoms in the IR spectra are frequently less reliable as indicators of the substitution pattern, especially in the presence of polar substituents, in which case their position tends to shift, and they often overlap with bands of substituents.

18.3.3.4 Synthesis of Aldosterone. Aldosterone synthesis is initiated by 21 -hydroxylation of progesterone to form 21 -hydroxyprogesterone, also known as deoxycorticosterone (Fig. 18-10). The subsequent steps in aldosterone synthesis involve two hydroxylation reactions at C 1 1 and C18, respectively, followed by oxidation of the C18 hydroxyl group to a keto group. These three steps are all catalyzed by the same enzyme, CYPl lB2. 18.3.3.5 Synthesis of Androgens. The pathway for the synthesis of testosterone in the testis is shown in Figure 18-11. Pregnenolone is first hydroxylated by CYP17 to 17-hydroxpregnenolone. CYP17 also has 17,20-lyase activity, thus allowing for the synthesis of dehydroepiandrosterone (DHEA). Synthesis of testosterone from DHEA involves successive hydroxylations by 3P-hydroxysteroid dehydrogenase (generating androstenedione) and then 17P-hydroxysteroid dehydrogenase. Both DHEA and androstenedione have weak androgenic activity and are synthesized in the adrenals as well as the gonads.

IGP and/or Label Distribution Protocol (LDP) with Equal Cost Multi-Paths (ECMP) allow traffic of a failed path to be re-distributed across remaining available paths. These resiliency features provide a reliable way to carry traffic through the backbone network and have the best failover performance. The resiliency features protect the transport tunnel in the backbone network. Therefore, these features can be categorized as network resiliency or backbone resiliency features. All services using the backbone network to transport traffic can take advantage of the enhanced robustness of the network. However, these features protect the services only from the failures along the service transport tunnel [the provider (P) routers and the links in the backbone]. Another possibility to consider is what happens if the service instance in a PE router fails, a pseudowire connecting two service instances fails, or if a PE router with many service instances fails. These failure scenarios are specific to the services; therefore, the backbone resiliency cannot protect the service against these failures. As discussed in 9, each VLL service has two member PE routers, and each member PE router has one Service Access Point (SAP) and one pseudowire. Each SAP connects one Customer Edge (CE) device. The entire VLL service provides a point-to-point Layer 2 connectivity between two customer sites. To improve the service resiliency, various redundancy mechanisms can be deployed in the network: Using Link Aggregation Group (LAG) to protect the attachment circuits on the SAP Using pseudowire redundancy to protect the service from a pseudowire failure Using Multi Chassis LAG (MC-LAG) with pseudowire redundancy to protect the SAP and the PE router failures Depending on the resiliency requirement for the services, network resources availability, and the network topology, the operator can choose from the above options to deploy VLL service resiliency.